A Family of Discrete Magnetically Switchable Nanoballs
Identifieur interne : 005742 ( Main/Exploration ); précédent : 005741; suivant : 005743A Family of Discrete Magnetically Switchable Nanoballs
Auteurs : Martin B. Duriska [Australie] ; Suzanne M. Neville [Australie, États-Unis] ; Boujemaa Moubaraki [Australie] ; Keith S. Murray [Australie] ; Chérif Balde [France] ; Jean-François Létard [France] ; Cameron J. Kepert [Australie] ; Stuart R. Batten [Australie, États-Unis]Source :
- ChemPlusChem [ 2192-6506 ] ; 2012-08.
English descriptors
- KwdEn :
- Analogue, Angew, Anion, Behaviour, Centre, Chem, Chempluschem, Considerable interest, Diffraction analysis, Elemental analysis, Elemental analysis calcd, Exponential behaviour, Feii, Feii centres, Feii metal centres, Feii sites, Final value, Gmbh, Green light, Halder, Infrared spectroscopy, Kepert, Kgaa, Liesst, Liesst activity, Liesst effect, Ligand, Light irradiation, Magnetic character, Magnetic properties, Magnetic response, Microcrystalline powders, Mmol, Molecules figure, Mononuclear materials, Moubaraki, Nanoball, Ncbh3, Ncse, Neville, Optical reflectivity, Photomagnetic, Photomagnetic properties, Photon source, Rapid decrease, Rapid increase, Reflectivity, Relaxation kinetics, Room temperature, Scorpionate ligand, Signal intensity, Small amount, Solvent variation, Stronger ligand fields, Synchrotron radiation, Syringe filter, Temperature range, Thermogravimetric analysis, Thin layer, Transition behaviour, Transition metal complexes, Transition temperature, Transition temperatures, Values decrease, Verlag, Verlag gmbh, Weinheim, Weinheim chempluschem, Yellow crystals, Yellow solution.
- Teeft :
- Analogue, Angew, Anion, Behaviour, Centre, Chem, Chempluschem, Considerable interest, Diffraction analysis, Elemental analysis, Elemental analysis calcd, Exponential behaviour, Feii, Feii centres, Feii metal centres, Feii sites, Final value, Gmbh, Green light, Halder, Infrared spectroscopy, Kepert, Kgaa, Liesst, Liesst activity, Liesst effect, Ligand, Light irradiation, Magnetic character, Magnetic properties, Magnetic response, Microcrystalline powders, Mmol, Molecules figure, Mononuclear materials, Moubaraki, Nanoball, Ncbh3, Ncse, Neville, Optical reflectivity, Photomagnetic, Photomagnetic properties, Photon source, Rapid decrease, Rapid increase, Reflectivity, Relaxation kinetics, Room temperature, Scorpionate ligand, Signal intensity, Small amount, Solvent variation, Stronger ligand fields, Synchrotron radiation, Syringe filter, Temperature range, Thermogravimetric analysis, Thin layer, Transition behaviour, Transition metal complexes, Transition temperature, Transition temperatures, Values decrease, Verlag, Verlag gmbh, Weinheim, Weinheim chempluschem, Yellow crystals, Yellow solution.
Abstract
The thermal and light‐induced magnetic properties of a family of discrete magnetically switchable “nanoball” species (3 nm in diameter) is reported. The self‐assembly of these materials is accomplished by the use of the metallo building block, [Cu([Tp4‐py])(NCCH3)] ([Tp4‐py]=tris‐[3‐(4'‐pyridyl)pyrazol‐1‐yl]hydroborate), combined with a [Fe(NCX)2] (X=S, Se and BH3) species. We previously showed that the thiocyanate analogue (Fe(NCS)‐nano) undergoes a thermal and light‐induced spin crossover (SCO)—the largest such discrete SCO material reported. Now included in this family are the Se and BH3 analogues, Fe(NCSe)‐nano and Fe(NCBH3)‐nano, which show increased thermal transition temperatures (T1/2=124 K, 162 and 173 K). This variation in transition temperature over the series S
Url:
DOI: 10.1002/cplu.201200123
Url:
DOI: 10.1002/cplu.201200123
Affiliations:
- Australie, France, États-Unis
- Aquitaine, Nouvelle-Aquitaine, Nouvelle-Galles du Sud
- Bordeaux, Sydney
- Université Bordeaux I, Université de Sydney
Links toward previous steps (curation, corpus...)
- to stream Istex, to step Corpus: 001B06
- to stream Istex, to step Curation: 001B06
- to stream Istex, to step Checkpoint: 000667
- to stream Main, to step Merge: 005A09
- to stream Main, to step Curation: 005742
Le document en format XML
<record><TEI wicri:istexFullTextTei="biblStruct"><teiHeader><fileDesc><titleStmt><title xml:lang="en">A Family of Discrete Magnetically Switchable Nanoballs</title><author><name sortKey="Duriska, Martin B" sort="Duriska, Martin B" uniqKey="Duriska M" first="Martin B." last="Duriska">Martin B. Duriska</name></author><author><name sortKey="Neville, Suzanne M" sort="Neville, Suzanne M" uniqKey="Neville S" first="Suzanne M." last="Neville">Suzanne M. Neville</name></author><author><name sortKey="Moubaraki, Boujemaa" sort="Moubaraki, Boujemaa" uniqKey="Moubaraki B" first="Boujemaa" last="Moubaraki">Boujemaa Moubaraki</name></author><author><name sortKey="Murray, Keith S" sort="Murray, Keith S" uniqKey="Murray K" first="Keith S." last="Murray">Keith S. Murray</name></author><author><name sortKey="Balde, Cherif" sort="Balde, Cherif" uniqKey="Balde C" first="Chérif" last="Balde">Chérif Balde</name></author><author><name sortKey="Letard, Jean Rancois" sort="Letard, Jean Rancois" uniqKey="Letard J" first="Jean-François" last="Létard">Jean-François Létard</name></author><author><name sortKey="Kepert, Cameron J" sort="Kepert, Cameron J" uniqKey="Kepert C" first="Cameron J." last="Kepert">Cameron J. Kepert</name></author><author><name sortKey="Batten, Stuart R" sort="Batten, Stuart R" uniqKey="Batten S" first="Stuart R." last="Batten">Stuart R. Batten</name></author></titleStmt><publicationStmt><idno type="wicri:source">ISTEX</idno><idno type="RBID">ISTEX:8F755B260F4D2C0191F5D625D93FEB8F2EA75E53</idno><date when="2012" year="2012">2012</date><idno type="doi">10.1002/cplu.201200123</idno><idno type="url">https://api.istex.fr/document/8F755B260F4D2C0191F5D625D93FEB8F2EA75E53/fulltext/pdf</idno><idno type="wicri:Area/Istex/Corpus">001B06</idno><idno type="wicri:explorRef" wicri:stream="Istex" wicri:step="Corpus" wicri:corpus="ISTEX">001B06</idno><idno type="wicri:Area/Istex/Curation">001B06</idno><idno type="wicri:Area/Istex/Checkpoint">000667</idno><idno type="wicri:explorRef" wicri:stream="Istex" wicri:step="Checkpoint">000667</idno><idno type="wicri:doubleKey">2192-6506:2012:Duriska M:a:family:of</idno><idno type="wicri:Area/Main/Merge">005A09</idno><idno type="wicri:Area/Main/Curation">005742</idno><idno type="wicri:Area/Main/Exploration">005742</idno></publicationStmt><sourceDesc><biblStruct><analytic><title level="a" type="main" xml:lang="en">A Family of Discrete Magnetically Switchable Nanoballs</title><author><name sortKey="Duriska, Martin B" sort="Duriska, Martin B" uniqKey="Duriska M" first="Martin B." last="Duriska">Martin B. Duriska</name><affiliation wicri:level="1"><country xml:lang="fr">Australie</country><wicri:regionArea>School of Chemistry, Monash University, Building 23, Clayton</wicri:regionArea><wicri:noRegion>Clayton</wicri:noRegion></affiliation></author><author><name sortKey="Neville, Suzanne M" sort="Neville, Suzanne M" uniqKey="Neville S" first="Suzanne M." last="Neville">Suzanne M. Neville</name><affiliation wicri:level="1"><country xml:lang="fr">Australie</country><wicri:regionArea>School of Chemistry, Monash University, Building 23, Clayton</wicri:regionArea><wicri:noRegion>Clayton</wicri:noRegion></affiliation><affiliation wicri:level="1"><country wicri:rule="url">États-Unis</country></affiliation><affiliation wicri:level="1"><country xml:lang="fr">Australie</country><wicri:regionArea>Correspondence address: School of Chemistry, Monash University, Building 23, Clayton</wicri:regionArea><wicri:noRegion>Clayton</wicri:noRegion></affiliation></author><author><name sortKey="Moubaraki, Boujemaa" sort="Moubaraki, Boujemaa" uniqKey="Moubaraki B" first="Boujemaa" last="Moubaraki">Boujemaa Moubaraki</name><affiliation wicri:level="1"><country xml:lang="fr">Australie</country><wicri:regionArea>School of Chemistry, Monash University, Building 23, Clayton</wicri:regionArea><wicri:noRegion>Clayton</wicri:noRegion></affiliation></author><author><name sortKey="Murray, Keith S" sort="Murray, Keith S" uniqKey="Murray K" first="Keith S." last="Murray">Keith S. Murray</name><affiliation wicri:level="1"><country xml:lang="fr">Australie</country><wicri:regionArea>School of Chemistry, Monash University, Building 23, Clayton</wicri:regionArea><wicri:noRegion>Clayton</wicri:noRegion></affiliation></author><author><name sortKey="Balde, Cherif" sort="Balde, Cherif" uniqKey="Balde C" first="Chérif" last="Balde">Chérif Balde</name><affiliation wicri:level="4"><country xml:lang="fr">France</country><wicri:regionArea>ICMCB, CNRS‐Université Bordeaux I, 87 Av. du Doc. A. Schweitzer</wicri:regionArea><orgName type="university">Université Bordeaux I</orgName><placeName><settlement type="city">Bordeaux</settlement><region type="region" nuts="2">Nouvelle-Aquitaine</region><region type="old region" nuts="2">Aquitaine</region></placeName></affiliation><affiliation></affiliation></author><author><name sortKey="Letard, Jean Rancois" sort="Letard, Jean Rancois" uniqKey="Letard J" first="Jean-François" last="Létard">Jean-François Létard</name><affiliation wicri:level="4"><country xml:lang="fr">France</country><wicri:regionArea>ICMCB, CNRS‐Université Bordeaux I, 87 Av. du Doc. A. Schweitzer</wicri:regionArea><orgName type="university">Université Bordeaux I</orgName><placeName><settlement type="city">Bordeaux</settlement><region type="region" nuts="2">Nouvelle-Aquitaine</region><region type="old region" nuts="2">Aquitaine</region></placeName></affiliation></author><author><name sortKey="Kepert, Cameron J" sort="Kepert, Cameron J" uniqKey="Kepert C" first="Cameron J." last="Kepert">Cameron J. Kepert</name><affiliation wicri:level="4"><country xml:lang="fr">Australie</country><wicri:regionArea>School of Chemistry, The University of Sydney</wicri:regionArea><placeName><settlement type="city">Sydney</settlement><region type="état">Nouvelle-Galles du Sud</region></placeName><orgName type="university">Université de Sydney</orgName></affiliation></author><author><name sortKey="Batten, Stuart R" sort="Batten, Stuart R" uniqKey="Batten S" first="Stuart R." last="Batten">Stuart R. Batten</name><affiliation wicri:level="1"><country xml:lang="fr">Australie</country><wicri:regionArea>School of Chemistry, Monash University, Building 23, Clayton</wicri:regionArea><wicri:noRegion>Clayton</wicri:noRegion></affiliation><affiliation wicri:level="1"><country wicri:rule="url">États-Unis</country></affiliation><affiliation wicri:level="1"><country xml:lang="fr">Australie</country><wicri:regionArea>Correspondence address: School of Chemistry, Monash University, Building 23, Clayton</wicri:regionArea><wicri:noRegion>Clayton</wicri:noRegion></affiliation></author></analytic><monogr></monogr><series><title level="j" type="main">ChemPlusChem</title><title level="j" type="sub">Board Members Issue</title><title level="j" type="alt">CHEMPLUSCHEM</title><idno type="ISSN">2192-6506</idno><idno type="eISSN">2192-6506</idno><imprint><biblScope unit="vol">77</biblScope><biblScope unit="issue">8</biblScope><biblScope unit="page" from="616">616</biblScope><biblScope unit="page" to="623">623</biblScope><biblScope unit="page-count">8</biblScope><publisher>WILEY‐VCH Verlag</publisher><pubPlace>Weinheim</pubPlace><date type="published" when="2012-08">2012-08</date></imprint><idno type="ISSN">2192-6506</idno></series></biblStruct></sourceDesc><seriesStmt><idno type="ISSN">2192-6506</idno></seriesStmt></fileDesc><profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Analogue</term><term>Angew</term><term>Anion</term><term>Behaviour</term><term>Centre</term><term>Chem</term><term>Chempluschem</term><term>Considerable interest</term><term>Diffraction analysis</term><term>Elemental analysis</term><term>Elemental analysis calcd</term><term>Exponential behaviour</term><term>Feii</term><term>Feii centres</term><term>Feii metal centres</term><term>Feii sites</term><term>Final value</term><term>Gmbh</term><term>Green light</term><term>Halder</term><term>Infrared spectroscopy</term><term>Kepert</term><term>Kgaa</term><term>Liesst</term><term>Liesst activity</term><term>Liesst effect</term><term>Ligand</term><term>Light irradiation</term><term>Magnetic character</term><term>Magnetic properties</term><term>Magnetic response</term><term>Microcrystalline powders</term><term>Mmol</term><term>Molecules figure</term><term>Mononuclear materials</term><term>Moubaraki</term><term>Nanoball</term><term>Ncbh3</term><term>Ncse</term><term>Neville</term><term>Optical reflectivity</term><term>Photomagnetic</term><term>Photomagnetic properties</term><term>Photon source</term><term>Rapid decrease</term><term>Rapid increase</term><term>Reflectivity</term><term>Relaxation kinetics</term><term>Room temperature</term><term>Scorpionate ligand</term><term>Signal intensity</term><term>Small amount</term><term>Solvent variation</term><term>Stronger ligand fields</term><term>Synchrotron radiation</term><term>Syringe filter</term><term>Temperature range</term><term>Thermogravimetric analysis</term><term>Thin layer</term><term>Transition behaviour</term><term>Transition metal complexes</term><term>Transition temperature</term><term>Transition temperatures</term><term>Values decrease</term><term>Verlag</term><term>Verlag gmbh</term><term>Weinheim</term><term>Weinheim chempluschem</term><term>Yellow crystals</term><term>Yellow solution</term></keywords><keywords scheme="Teeft" xml:lang="en"><term>Analogue</term><term>Angew</term><term>Anion</term><term>Behaviour</term><term>Centre</term><term>Chem</term><term>Chempluschem</term><term>Considerable interest</term><term>Diffraction analysis</term><term>Elemental analysis</term><term>Elemental analysis calcd</term><term>Exponential behaviour</term><term>Feii</term><term>Feii centres</term><term>Feii metal centres</term><term>Feii sites</term><term>Final value</term><term>Gmbh</term><term>Green light</term><term>Halder</term><term>Infrared spectroscopy</term><term>Kepert</term><term>Kgaa</term><term>Liesst</term><term>Liesst activity</term><term>Liesst effect</term><term>Ligand</term><term>Light irradiation</term><term>Magnetic character</term><term>Magnetic properties</term><term>Magnetic response</term><term>Microcrystalline powders</term><term>Mmol</term><term>Molecules figure</term><term>Mononuclear materials</term><term>Moubaraki</term><term>Nanoball</term><term>Ncbh3</term><term>Ncse</term><term>Neville</term><term>Optical reflectivity</term><term>Photomagnetic</term><term>Photomagnetic properties</term><term>Photon source</term><term>Rapid decrease</term><term>Rapid increase</term><term>Reflectivity</term><term>Relaxation kinetics</term><term>Room temperature</term><term>Scorpionate ligand</term><term>Signal intensity</term><term>Small amount</term><term>Solvent variation</term><term>Stronger ligand fields</term><term>Synchrotron radiation</term><term>Syringe filter</term><term>Temperature range</term><term>Thermogravimetric analysis</term><term>Thin layer</term><term>Transition behaviour</term><term>Transition metal complexes</term><term>Transition temperature</term><term>Transition temperatures</term><term>Values decrease</term><term>Verlag</term><term>Verlag gmbh</term><term>Weinheim</term><term>Weinheim chempluschem</term><term>Yellow crystals</term><term>Yellow solution</term></keywords></textClass></profileDesc></teiHeader><front><div type="abstract">The thermal and light‐induced magnetic properties of a family of discrete magnetically switchable “nanoball” species (3 nm in diameter) is reported. The self‐assembly of these materials is accomplished by the use of the metallo building block, [Cu([Tp4‐py])(NCCH3)] ([Tp4‐py]=tris‐[3‐(4'‐pyridyl)pyrazol‐1‐yl]hydroborate), combined with a [Fe(NCX)2] (X=S, Se and BH3) species. We previously showed that the thiocyanate analogue (Fe(NCS)‐nano) undergoes a thermal and light‐induced spin crossover (SCO)—the largest such discrete SCO material reported. Now included in this family are the Se and BH3 analogues, Fe(NCSe)‐nano and Fe(NCBH3)‐nano, which show increased thermal transition temperatures (T1/2=124 K, 162 and 173 K). This variation in transition temperature over the series S</div> </front></TEI><affiliations><list><country><li>Australie</li><li>France</li><li>États-Unis</li></country><region><li>Aquitaine</li><li>Nouvelle-Aquitaine</li><li>Nouvelle-Galles du Sud</li></region><settlement><li>Bordeaux</li><li>Sydney</li></settlement><orgName><li>Université Bordeaux I</li><li>Université de Sydney</li></orgName></list><tree><country name="Australie"><noRegion><name sortKey="Duriska, Martin B" sort="Duriska, Martin B" uniqKey="Duriska M" first="Martin B." last="Duriska">Martin B. Duriska</name></noRegion><name sortKey="Batten, Stuart R" sort="Batten, Stuart R" uniqKey="Batten S" first="Stuart R." last="Batten">Stuart R. Batten</name><name sortKey="Batten, Stuart R" sort="Batten, Stuart R" uniqKey="Batten S" first="Stuart R." last="Batten">Stuart R. Batten</name><name sortKey="Kepert, Cameron J" sort="Kepert, Cameron J" uniqKey="Kepert C" first="Cameron J." last="Kepert">Cameron J. Kepert</name><name sortKey="Moubaraki, Boujemaa" sort="Moubaraki, Boujemaa" uniqKey="Moubaraki B" first="Boujemaa" last="Moubaraki">Boujemaa Moubaraki</name><name sortKey="Murray, Keith S" sort="Murray, Keith S" uniqKey="Murray K" first="Keith S." last="Murray">Keith S. Murray</name><name sortKey="Neville, Suzanne M" sort="Neville, Suzanne M" uniqKey="Neville S" first="Suzanne M." last="Neville">Suzanne M. Neville</name><name sortKey="Neville, Suzanne M" sort="Neville, Suzanne M" uniqKey="Neville S" first="Suzanne M." last="Neville">Suzanne M. Neville</name></country><country name="États-Unis"><noRegion><name sortKey="Neville, Suzanne M" sort="Neville, Suzanne M" uniqKey="Neville S" first="Suzanne M." last="Neville">Suzanne M. Neville</name></noRegion><name sortKey="Batten, Stuart R" sort="Batten, Stuart R" uniqKey="Batten S" first="Stuart R." last="Batten">Stuart R. Batten</name></country><country name="France"><region name="Nouvelle-Aquitaine"><name sortKey="Balde, Cherif" sort="Balde, Cherif" uniqKey="Balde C" first="Chérif" last="Balde">Chérif Balde</name></region><name sortKey="Letard, Jean Rancois" sort="Letard, Jean Rancois" uniqKey="Letard J" first="Jean-François" last="Létard">Jean-François Létard</name></country></tree></affiliations></record>Pour manipuler ce document sous Unix (Dilib)
EXPLOR_STEP=$WICRI_ROOT/Wicri/Asie/explor/AustralieFrV1/Data/Main/Exploration
HfdSelect -h $EXPLOR_STEP/biblio.hfd -nk 005742 | SxmlIndent | more
Ou
HfdSelect -h $EXPLOR_AREA/Data/Main/Exploration/biblio.hfd -nk 005742 | SxmlIndent | more
Pour mettre un lien sur cette page dans le réseau Wicri
{{Explor lien
|wiki= Wicri/Asie
|area= AustralieFrV1
|flux= Main
|étape= Exploration
|type= RBID
|clé= ISTEX:8F755B260F4D2C0191F5D625D93FEB8F2EA75E53
|texte= A Family of Discrete Magnetically Switchable Nanoballs
}}
| This area was generated with Dilib version V0.6.33. |  |